No.
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It can't be one. Mixed numbers are greater than 1.
An improper fraction is where the numerator (number on top) is greater than the denominator (number on bottom). Your fraction 12/18 is proper, but it is not simplified. The simplified form is 2/3, which in decimal is 0.66666....
Neither is. Their values are identical.
16/25 is greater than 12/23
5/12 is greater than 3/8.