There's only one color that's equal to brown. That color is . . . brown.
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Complementary colors are opposite each other on the color wheel. When you mix two complementary colors you get brown. If you are painting a shadow you use the complement of the color the shadow falls on.
Let's start with what colors have complements red and green blue and orange yellow and purple one of the colors in the pairs is a primary (where no colors can be mixed to make that color) and the other color is a secondary that cannot be made by two other primary colors that are not of its complement (green is made of blue and yellow while it's complement is red) if you mix any two complementary colors, it will make brown. However, since brown is made of a primary (red, blue, or yellow) and a secondary (green, orange, or purple) color it doesn't have a complement because it isn't a primary nor a secondary color. Black is made of equal parts of all three primary colors while white is no color. I don't think they are considered complementary colors, but the fact that brown has no complement, they answer to the question would be no. Not every color has a complement.
brown
White color is produced when all three primary colors are mixed in equal amount. White color is seen when the three primary colors are reflected equally towards our eyes.
Three colors that are equal distance apart on the color wheel make up the triadic color scheme. Red, blue, and yellow are one of the most commonly used harmonious colors in this color scheme.