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DelocalisedThe term 'delocalised' refers to an electron which is not 'attached' to a particular atom. For example, in metals, some of the outer electrons are delocalised and are free to move around the whole metal solid. This is why metals conduct electricity.

Another example of delocalised electrons is in benzene (C6H6), a cyclic molecule composed of a ring of bonded carbons, with one hydrogen attached to each. In benzene, the electrons in the C-C pi-bonds (basically the double bonds) are delocalised the whole molecule. If you look at the location of these pi-bonding electrons, they are found evenly distributed in a ring around the entire molecule. In this case, the delocalisation can be explained by something called 'resonance forms.' Often, molecules with alternating double bonds show delocalised bonding.

However, to truly understand the concept of delocalisation, some basic quantum mechanics must be used, and delocalised bonding in molecules is best explained by molecular orbital theory. In reality, all electrons are somewhat delocalised and are never associated with exactly one bond (in molecules with more than 2 atoms). Some are more localised than others (specific electrons stay mostly with specific bonds), while some are more delocalized (electrons are very free to move about many different bonds in the molecule)

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Q: What does delocalized mean?
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Related questions

What does the term free moving electrons mean?

delocalized electrons


Are the pie bonds in NO2- delocalized?

Yes, the pi bonds in NO2- are delocalized. The nitrogen atom has a lone pair that can participate in resonance, allowing the pi bonds to be spread over the entire molecule.


What does aromatic mean?

Aromatic means "fragrant or spicy", or, in organic chemistry, "having a closed ring of alternate single or double bonds with delocalized electrons".


Is it true or false that physical properties of metals are independent of the number of delocalized electrons they have?

False. The physical properties of metals, such as conductivity and ductility, are influenced by the number of delocalized electrons they have. More delocalized electrons generally result in better conductivity and other related properties.


Why metal are good electrical conductivity?

Delocalized valence electrons


How can you know a localized and delocalized chemical bond?

What are lacalized bond


What bonds are formed by delocalized electrons in an Electron Sea?

metallic bond


What is delocalized?

metallic bonding happens because the electrons are attracted to more than one nucleus and hence more stable.the electrons are said to be delocalized


Are pi bonds are only delocalized bonds?

No, pi bonds are not the only delocalized bonds. Delocalized bonds refer to bonds where the electrons are not localized between two specific atoms but spread out over multiple atoms. Pi bonds are a type of delocalized bond, but other examples include aromatic bonds in benzene rings and resonance structures in molecules like nitrate (NO3-).


Free-electron gas in metals?

Electrons in metals are delocalized and in a free movement.


How do you rank the bond types by increasing delocalization of the valence electrons of least delocalized equals 1 and most delocalized equals 4 A Ionic Metallic B Polar covalent C Pure covalent?

Ionic - least delocalized electrons due to transfer of electrons from one atom to another. Pure covalent - electrons are shared equally between atoms in a bond, leading to localized electrons. Polar covalent - electrons are shared unequally between atoms, causing partial electron delocalization. Metallic - most delocalized electrons due to delocalized electron sea that allows electrons to move freely throughout the metal lattice.


Which of the following properties can be attributed to the fact that the electrons are delocalized and are able to move freely in metallic crystals?

High electrical conductivity, high thermal conductivity, and malleability can be attributed to the delocalized electrons in metallic crystals.