The honeycomb cells are in the form of a tessellated regular hexagon (six equal sides).
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The hexagon is one of the geometric shapes that occurs in nature. Found in the formation of honeycomb it is associated with bees and their co-operative, hard-working natures.
A couple of general observations: All shapes are geometric shapes. They may not be regular but they are still geometric. But, at a sufficiently detailed level, none of them will be geometric because all geometric shapes are ideals. A sphere, in nature is likely to be rough - at the molecular level - and so not precisely spherical. Subject to those two comments, how about: Stars (including the sun): spheres. Table salt (NaCl) crystal: cube Honeycomb : hexagonal based prism Carbon tetrachloride or methanr molecules: tetrahedra.
geometric
The Urban Dictionary lists 14 definitions for "shap," most of which can't be reprinted here. There is a possibility you meant "shape," which comes from an old German word meaning "creation."
Not sure about a five sided shap, but a five sided plane shape is called a pentagon.