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Could you please specify which postulate you are referring to?
Yes, triangles ABC and DEF are congruent if all corresponding sides and angles are equal. The congruence postulate that applies in this case could be the Side-Angle-Side (SAS) postulate, which states that if two sides and the included angle of one triangle are equal to two sides and the included angle of another triangle, then the triangles are congruent. Other applicable postulates include Side-Side-Side (SSS) and Angle-Angle-Side (AAS), depending on the known measurements.
When a postulate has been proven it becomes a theorem.
AAS stands for Angle Angle and Side