It is 6*6-5 = 6-4 = 1/1296 = 0.00077 (approx).
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1/1296 (0.07716%)
Well, what is the question?
Rolling it once there is a 1 out of 6 chance - because there is 6 numbers on a dice and one of them is three. so rolling it twice would be a 2 out of 12 chance / 0.16 / 16% chance
1/6 chance. Or a 16% chance
With a normal number cube, there is no chance at all.