They are the same thing.
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vertices are the corners of something fo example a square has 4 vertices and a vertex is the point of intersection of lines or the point opposite the base of a figure
In a polyhedron, there are edges, faces, and corners. The thing that is similar, or common, between the edges, faces, and corners are the vertices.
Corners.
Vertices are corners. Thus, there are 4 corners in a square.
A rectangular prism has 8 vertices/corners.