The molecular geometry of a molecule with two electron groups composed only of bonded pairs is linear. This occurs because the two bonding pairs are positioned 180 degrees apart to minimize electron pair repulsion, resulting in a straight-line arrangement. An example of such a molecule is carbon dioxide (CO₂).
trigonal planar
Electron pair geometry considers both bonding and lone pairs of electrons around a central atom, while molecular geometry focuses solely on the arrangement of bonded atoms. This can lead to different geometries when there are lone pairs present; for example, in ammonia (NH₃), the electron pair geometry is tetrahedral due to one lone pair, but the molecular geometry is trigonal pyramidal. The presence of lone pairs affects bond angles and the overall shape of the molecule, resulting in distinct geometries.
The molecular geometry of mercury(II) chloride (HgCl2) is linear. This is due to the presence of two chloride ions bonded to the central mercury atom, and the molecule adopts a linear shape to minimize electron pair repulsion. The bond angle in HgCl2 is approximately 180 degrees.
tetrahedral due to the four area of electron density (two loan pair electrons and two bonded pairs).
The electron geometry of OCN⁻ (cyanate ion) is trigonal planar, as it has three regions of electron density around the central carbon atom: one double bond to oxygen and a single bond to nitrogen, along with a lone pair of electrons. The molecular geometry is also trigonal planar because the lone pair does not affect the shape in this case, allowing for the same arrangement of the bonded atoms.
trigonal planar
The molecular geometry for a molecule with two electron groups and only bonded pairs is linear.
Electron pair geometry considers both bonding and lone pairs of electrons around a central atom, while molecular geometry focuses solely on the arrangement of bonded atoms. This can lead to different geometries when there are lone pairs present; for example, in ammonia (NH₃), the electron pair geometry is tetrahedral due to one lone pair, but the molecular geometry is trigonal pyramidal. The presence of lone pairs affects bond angles and the overall shape of the molecule, resulting in distinct geometries.
The presence of 1 lone pair in a molecule affects its molecular geometry by causing repulsion that pushes the bonded atoms closer together. This can lead to a distortion in the molecule's shape, often resulting in a bent or angular geometry.
This is a linear molecule.
The molecular geometry of a molecule with a tetrahedral pyramidal shape is called trigonal pyramidal. It has a central atom bonded to three atoms and one lone pair, resulting in a pyramid-like structure.
The electron domain geometry of XeF2 is linear. This is because the central atom Xe has two bonded atoms (F) and no lone pairs of electrons, resulting in a linear molecular geometry.
The molecular geometry of CS2 is linear. This molecule consists of a central carbon atom bonded to two sulfur atoms, and there are no lone pairs on the central atom. The bonds and atoms are arranged in a straight line, giving it a linear molecular geometry.
Electron pairs
In molecular geometry, bond length refers to the distance separating nuclei of bonded atoms in a single molecule.
tetrahedral due to the four area of electron density (two loan pair electrons and two bonded pairs).
The molecular geometry characterized by 109.5 degree bond angles is tetrahedral. This geometry occurs when a central atom is bonded to four surrounding atoms with no lone pairs on the central atom. An example of a molecule with this geometry is methane (CH4).