It is acceptable to call it a 101-agon
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the name of the polygon with 101 sides is hecatontakaihenagon
it will depend on the size of the polygon or, what polygon it is.
There is no formula for how many sides there are in a polygon; the name of the polygon shows how many sides it has.
There is not a name for such a polygon. A polygon with one million sides is called a megagon though..
A polygon with 4 sides is a quadrilateral.