It doesn't. Please revise your basic geometry & mensuration.
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6 cm is a unit of length, and length cannot be converted to volume. It would be like saying, "how many miles are in a gallon of milk?" It just doesn't work.
Volume = 2*4*6 = 48 cubic cm
Since the formula for volume of a cube is s to the 3rd power, the answer would be 6 to the 3rd power, which equals 216
A base AREA cannot be 6 cm. Area is measured in square units of measure. If the base area is 6 cm2 then the volume is 6*7 = 42 cm3 and pi does not enter into the calculations at all.
6 cm.