If, by base, you mean alkali, then 14.
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Base 2
There is no smallest number, in any base.
A base number is the value to the power of the exponent. For example, in 2^4, 2 is the base number and 4 is the exponent.
In their simplest forms, a base number is the number that is being multiplied by itself while the exponent is the number of times that the base is multiplied.
Probably it was the ancient Babylonians whose number base was 60 or maybe the ancient Mayans whose number base was 20