A side is the same thing as a face.
A quadrilateral based pyramid or triangular prism are the two possible polyhedra.
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Five faces (it is a 3 dimensional shape). A four sided pyramid is a pentahedron. (penta- means five, -hedron means sides)
Shapes have sides. Do you mean, what shape has 6 sides or, what solid has 6 faces?
With great difficulty since such a shape cannot exist. A cuboid, by definition, has six faces (sides).
A shape's sides are called faces.
It is not possible to have five perpendicular sides; four or eight, but not five. A shape with five equal sides is a pentagon.