With two normal six-sided dice, the maximum sum can only be 12 (6 x 2 dice), so there is zero probability of rolling a sum that adds to 16.
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Assuming these are regular dice, the probability is 1.
If 2 standard dice are rolled, the odds of getting a sum of 16 is zero. The highest sum possible is 12.
The probability of rolling 12 with 2 dice is 1 in 36. The probability of not rolling 12 with 2 dice is 35 in 36.
Probability that the sum is 6 = 5/36 Probability that the sum is 7 = 6/36
1/12