They are: 23+2 = 25
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23 and 29
37 and 5
If two prime number have a sum of 54 they cannot have a sum of 84, and conversely.
It is impossible for the product of two prime numbers to be prime. It is impossible for the sum of two prime numbers to be prime as long as one of the numbers isn't 2.
If you meant "what two prime numbers have a sum of 36?" the answer is 19 and 17.