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2-butene is more stable than 1-butene due to the greater degree of alkyl substitution at the double bond. In 2-butene, the double bond is flanked by two alkyl groups, which provide hyperconjugation and electron-donating effects that stabilize the double bond. In contrast, 1-butene has only one alkyl group adjacent to the double bond, leading to less stabilization. Consequently, the increased substitution in 2-butene contributes to its overall stability.

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