A kilogram is a unit of mass; a hectare is a unit of area. There is no standard conversion between the two. If you say "kg per ha", presumably you need a certain amount of a certain substance, for example, to spray a hectare. This will vary from one substance to another. The amount, 2.24, only applies to one specific substance, and for one specific purpose.
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You cannot. Kilogram per hectare is a measure of mass per area whereas part per million is a pure ratio - without units. According to basic principles of dimensional analysis, any attempt at conversion from one to the other is fundamentally flawed.
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