road distances in km. measurements in metres or even smaller
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You can use the kilometer to measure small distances, but it is inconvenient to do so. A kilometer is a unit of measurement for a large distance. It is more accurate and practical to measure small distances using smaller units like the meter or centimeter.
Length
Liters cannot convert to kilometers. A liter is a measure of volume, a meter, or kilometer, is a measure of length. Liters are a measure of volume, and kilometers are a measure of distance, so there is no equivalence between the two measures. It would be like asking how many quarts are equal to 6 miles.
A centimetre. A centimetre. A centimetre. A centimetre.
Centimetre, metre and kilometre are measures of distance in order of increasing size. A millilitre, is not a measure of distance and so cannot be compared with them.