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I assume you're asking about gaseous oxygen, not liquified oxygen. Volume of any gas depends on the pressure. A pound of oxygen can fill as many gallons as the container allows under that pressure. Since it's a gas it expands in the area allowed. Hope that makes sense.
== In case you're talking about liquid oxygen, it weighs about 9.52 pounds per gallon. Your pound of liquid oxygen is about 1 2/3 cups of this cryogenic stuff.
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