You don't. Pascals is used to measure pressure, centigrade is used to measure temperature. Those two are completely different things.
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1 bar = 105 Pascals (Pa)
To convert atmosphere (atm) to pascals (Pa), multiply the value in atm by 101,325 (the number of pascals in 1 atm). For example, 1 atm is equal to 101,325 Pa.
To convert pascals to megapascals, divide the pressure value in pascals by 1,000,000. For instance, to convert 5,000,000 pascals to megapascals, you would divide 5,000,000 by 1,000,000 to get 5 megapascals.
To convert tons to Mega pascals, you need to specify the material's density or stress. The conversion factor will depend on this information. Without that, a direct conversion from tons to Mega pascals is not possible.
To convert form Centigrade (= Celsius) to Kelvin, add 273.