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From my knowledge i know that in case you want to make a salt that contains sodium, potassium, Ammonium ions [very reactive ions], u gotta use this method...Basically u put a known amount of ur solid in a glass tube..The metal is heated and a group 7 non-metal such as...dry chlorine is passed into the glass tube... After some time..Anhydrous salt will be formed... [note: Inside the glass tube, its a vacumn which means theres no air or water]

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