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"As a system approaches absolute zero, all processes cease and the entropy of the system approaches a minimum value."

"it is impossible by any procedure, no matter how idealised, to reduce any system to the absolute zero of temperature in a finite number of operations".

Lewis (of Lewis acids and bases fame) and Merle Randall phrased it as

"If the entropy of each element in some (perfect) crystalline state be taken as zero at the absolute zero of temperature, every substance has a finite positive entropy; but at the absolute zero of temperature the entropy may become zero, and does so become in the case of perfect crystalline substances."

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The third law of thermodynamics, formulated by Ludwig Boltzmann, states that as the temperature of a system approaches absolute zero, the entropy of the system also approaches zero. In simpler terms, it implies that a system at absolute zero temperature has minimal disorder, or entropy.

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10mo ago
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The entropy of a perfect crystal at 0 k is zero.

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Q: What is the third law of thermodynamics as defined by Ludwig Boltzmann?
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Continue Learning about Natural Sciences

What is a precious stone with third letter w?

The word is jewel. It is defined as a precious stone.


How many thermodynamics laws are there?

There are three laws of thermodynamics. The first law states that energy cannot be created or destroyed, only transformed. The second law states that heat naturally flows from hot to cold. The third law states that as temperature approaches absolute zero, the entropy of a perfect crystal approaches zero.


How do you know the third law of thermodynamics is true?

The third law of thermodynamics, which states that the entropy of a perfect crystal approaches zero as the temperature approaches absolute zero, is supported by experimental evidence and observations. Numerous experiments and studies have confirmed that as a system reaches absolute zero, its entropy decreases to a minimum value, in accordance with the third law of thermodynamics.


What states that the two system which are in thermal equilibrium with a third system are in thermal equilibrium with each other?

The Zeroth Law of Thermodynamics states that if two systems are in thermal equilibrium with a third system, then they are in thermal equilibrium with each other. This law establishes the concept of temperature and allows for the definition of a common temperature scale.


Could you review the laws of thermodynamics?

Sure! The laws of thermodynamics are fundamental principles of energy and heat transfer in physical systems. The first law states that energy cannot be created or destroyed, only transferred or converted. The second law states that heat naturally flows from higher to lower temperature regions, and it is impossible to completely convert heat into work without producing some waste heat. The third law states that as temperature approaches absolute zero, the entropy of a perfect crystal approaches zero.