which halogen naturally exit in + ve oxydation state
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Fluorine is the only halogen that does not naturally exist in any positive oxidation state. The other halogens - chlorine, bromine, iodine, and astatine - can exist in various positive oxidation states, though they are less common in nature compared to their negative oxidation states.
Chlorine belongs to halogen family. chlorine exists as diatomic molecule in nature.
Period 5 of the periodic table includes the halogen element bromine (Br). It is a highly reactive nonmetal and exists as a diatomic molecule in its natural state.
Helium does not readily form compounds and typically exists in its elemental form, which is neutral with an oxidation state of 0.
Sulfur
Less than one ounce of astatine exists on Earth. It was discovered by D.R. Corson, K.R. MacKenzie and E. Segre in 1940.