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300 ml is a measure of volume. A decimal is a number - pure and simple - neither mass, nor volume, neither length not time. So there is no decimal that is the same as 300 ml.
You cannot add things with units to things without units. "300mL" has a unit. "2/3" does not. Please resubmit your question where both items either have units or do not.
300/1,000 = 3/10
None. A decimal is a pure number, with no measurement units associated with it. A millilitre is a measure of volume. According to the basic principles of dimensional analysis, conversion between a dimensionless number and a measure of volume is not valid.