Most mathematicians use "100-gon." Hectogon and centagon are also permissible.
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100 sided shape is called a hectagon (apparently, this is according to another website :] )
Its probley a 100 gon. a polygon that has more than 12 side is a 13 and up gon. the only shape below 12 is an eleven sided shape, its called a 11 gon. lol
The 22 sided shape is called a: ICOSIKAIDIGON
Hommasquabblelagagon
A five-sided shape is called a pentagon.