Pounds is a unit of weight (or force). Quarts is a unit of volume.
They are different things and cannot be converted into each other.
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To convert 25 pounds into metric measurements: 2.20462 lb = 1 kg Therefore divide by 2.20462: 25 lb = 25 / 2.20462 kg/lb = 11.34 kg
Quarts are a measure of liquid volume. Pounds is a measure of weight/mass. They don't convert directly because of density. However, water can typically be said to match the weight and volume. A quart is 32 ounces. In this case the conversion would be 64 pounds.
13 quarts = 26 pints. That's more than 25.
You multiply by 946.35.
1 Gram of water 1x1,000 = I liter of water 0.946352946 quarts = 1 liter 0.946352945 x 2.5 = 2.365882365 liters 2.365882365 x 1,000 = 2365.882365 grams of water 453.59237 grams = 1 pound 2365.882365 / 453.59237 = 5.215877782512082 pounds in 2.5 quarts of water