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There are 1000 micrograms in a milligram. Therefore, you multiply by 1000 here. 5 milligrams is 5x1000 or 5,000 micrograms.
345,000 = (3 x 100000) + (4 x 10000) + (5 x 1000) + (0 x 100) + (0 x 10) + (0 x 1)