All it would be called would be a 100000000000000000000000-gon. I know it may sound dumb but that's the answer.
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Well, isn't that a happy little question! That shape is called a "hecatontakaitrigon." Just imagine all the wonderful colors and patterns you could paint on each of those sides - what a joyous and creative adventure that would be!
A shape with 100,000,000,000,000,000,000,000 sides is called a hecatontakaitrigon. The prefix "hecatontakai" denotes 100 sides, and the suffix "-gon" signifies a shape with that many sides. This shape would be a polygon, specifically a regular one with all sides and angles equal.
Oh, dude, that's like a googolgon. Yeah, I know, sounds like something out of a cartoon, right? But hey, that's the technical term for a shape with a gazillion sides. So next time you need to impress someone with your math skills, just drop that little gem on them.
The 22 sided shape is called a: ICOSIKAIDIGON
Hommasquabblelagagon
A five-sided shape is called a pentagon.
A 10-sided shape is called a decagon.
It is called a megagon. A ∞ sided shape is called an apeirogon.