A reduced chi-square value, calculated after a nonlinear regression has been performed, is the is the Chi-Square value divided by the degrees of freedom (DOF). The degrees of freedom in this case is N-P, where N is the number of data points and P is the number of parameters in the fitting function that has been used. I have added a link, which explains better the advantages of calculating the reduced chi-square in assessing the goodness of fit of a non-linear regression equation. In fitting an equation to the data, it is possible to also "over fit", which is to account for small and random errors in the data, with additional parameters. The reduced chi-square value will increase (show a worse fit) if the addition of a parameter does not significantly improve the fit. You can also do a search on reduced chi-square value to better understand its importance.
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Chi-square is a distribution used to analyze the standard deviation of two samples. A t-distribution on the other hand, is used to compare the means of two samples.
The chi-square test is pronounced "keye-skwair" test.
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Critical values of a chi-square test depend on the degrees of freedom.
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