The usual polygon names only extend to 20 sides.
A 46-sided polygon is a tetracontahexagon using the Greek prefixes.
For the molecular structure of alkanes, the terminology would be reversed
(hexatetracontagon).
(see the related link below)
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Decagon. A decagon is the name of a ten sided shape.
A 10-sided shape is a decagon.
A Pentacontagon is a fifty sided shape ...
hundred sided shape is called a chlligon
A 70 sided shape is called a heptacontagon.