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The main problem is that the question makes no sense at all.

A milligram is a measure of mass. A centilitre is a measure of volume. The two measure different things and, according to basic principles of dimensional analysis, conversion from one to the other is not valid.

If you are not convinced, consider a centilitre of air. How many milligrams? Next consider a centilitre of water. How many milligrams?

The masses of equal volumes of the two substances will clearly be very different. So there is no direct conversion between mass and volume: you need to know the density of the substance to enable you to carry out the conversion.

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Q: What is this problem of this 100 cl -------- mg?
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