Without knowing the width and lengh of the 25 acre parcel your question is impossible to answer. If your plot was completely square, your periphery would be 0.79 miles. But if your plot a mile long and 206feet wide your periphery will be 2.07 miles long.
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It all depends on the shape. Rectangle, oval, square or triangle for example. The smallest would be circular, with a diameter of just over 1053 feet, which would be 0.63 of a mile