Yes, there are two cent stamps. They have been available almost since the first stamps were issued. For many decades the postage rate in the US was two cents. Today they are mostly used to add to other stamps to make up a new rate.
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Dozen is a word used to represent a grouping of twelve items. Therefore there would be twelve two-cent stamps in a dozen stamps.
The question is usually put as follows: If there are 12 "1 cent" stamps in a dozen, how many "2 cent" stamps are there?" The answer is still 12 "2 cent" stamps in a dozen.