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There are no capital cities of sovereign countries beginning with X. There are four capital cities beginning with Y, and one beginning with Z. These are the following (alongside their respective countries):
Yamoussoukro (Côte d'Ivoire (official))
Yaoundé (Cameroon)
Yaren (Nauru (administrative))
Yerevan (Armenia)
Zagreb (Croatia)
Xalapa is a city in Mexico. It is the capital city of the Mexican state Veracruz.
Zagreb is the capital city in Croatia. Zhengzhou is the capital city in Henan Province, China.