Significant figures rules:
If it's a whole number like 325, there are 3 sig figs.
If it's a whole number like 320, there are 2 (zero doesn't count here).
If it's 320. (with the decimal), there are 3.
Zeroes after the decimal number don't count. (.23400 has 3 sig figs.)
Zeroes to the left of the numbers do. (.00234 has 5 sig figs).
If you've got a combination like .0023400, there are still only 5 sig figs.
Something like 37192 would have 5 sig figs. So would .00001. So would 95.002.
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That one has five.
3.14159265358979 to five significant figures is 3.1416
Five significant figures.
38.080C has five significant figures.
Five significant figures.