Where the electron pair is in the structure is important, because every molecule assumes a particular structure because it is lowest in energy ( it conserves the most energy and is more stable relative to other conformations). the "See-saw"structure (where the electron pair occupies an equitorial position) is a lower-energy structure than "trigonal pyramidal"(electron pair occupies an axial position- top or botom) because the electron pair has more electronegativity than the bonded atoms, and therefore occupies the position with the most space from all other substituent atoms (if the electron cloud is in the axial position, all 3 adjacent atoms are 90 degrees from it, where if the electron pair is in an equitorial position, it is 120 degrees from 2 atoms and 90 degrees from the other 2).
Look at the bond angle of hydrogens on NH3 or H2O and you can see how electron pairs actually force other atoms bonded to the central atom closer to each other (the H-N-H bond angle in NH3 is 107.8 degrees and H-O-H bond angle in H2O is 104.5 degrees, whereas 109.5 degrees for tetrahedron molecules, such as CH4 is the case of all atoms are the same (H-C-H)).
For moreinformation, go to: wikipedia's "Molecular geometry" page
The molecular shape of SCl6 is octahedral.
The molecular shape for CHI3 is trigonal bipyramidal.
The molecular shape name for C3H8 is a tetrahedron.
Parent Shape: Trigonal bipyrimidal Actual shape: Trigonal Planar
V-shape
A compound that does not have a bent molecular shape is carbon dioxide (CO2). It has a linear molecular shape due to the arrangement of the three atoms in a straight line.
The molecular shape of a magnesium hydride molecule is linear. Magnesium has a +2 charge, while hydride has a -1 charge, resulting in a linear molecular shape.
The molecular shape of CIF2 is linear. This is because there are only two atoms bonded with the central atom, which results in a linear molecular geometry.
Isomers
F2 has a linear shape.
The shape of SF4 is Sea Saw
The bond angle in silicon disulfide (SiS2) is approximately 105 degrees, and the molecular shape is bent/angular.