Well, honey, 2 liters is the same as 2000 milliliters. And since there are 1000 milliliters in a liter, you just move that decimal point over to the left once to get 2.0 in decimal form. So, the decimal form of 2 liters is 2.0.
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2 is a number in decimal form. Litre is a unit of measurement and in terms of decimal, it is irrelevant.