hexahedron is the name of a 3d hexagon
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There is no such thing as a 3d hexagon. Regular hexagons cannot form a 3d shape.
A hexagonal pyramid
A hexagon is a 2d shape with six sides, a hexahedron is a 3d shape with six faces.
If it is a an hexagonal prism then it will have 12 vertices
A hexagon based pyramid.