This is not a great explanation but I'll try.
The gogaplex was invented by some crazy mathematician who basically said that you keep writing 0's after a 1 till your hand gets tired. It has come to 100 0's after a 1 or 1*10^100. It is 1 followed by a googol of 0's which is 100.
What you have, googleplex, is a building for the corporate headquarters for Google.
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