As long as you can put it into some liquid, very easily. Just measure the volume of the liquid before and after you put the shape in.
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No not really
Of course, Squares and Rectangles are 2D shapes, therefore they don't have volumes. However, if you are asking what the volume of a cube is, the equation is; Width X Length X Height = Volume of a cube (or cuboid) Hope that -rant removed for idiocy-
measure it in a graduated cylinder
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Finding the volume of many odd shapes is only possible with integral calculus. Google " volume of revolution. "