There is no way to work out the angles in a general polygon. The sum of the interior angles of a polygon, with n sides, is (n-2)*pi radians [or (n-2)*180 degrees]. Therefore, if you know the measure of n-1 angles, you can work out the size of the nth angle.
Alternatively, if the polygon is one of the rare type - a regular polygon - then all its angles are equal. In that case, you can divided the above sum by n.
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A Regular Polygon
a polygon that has all angles congruent is an equiangular .....
A polygon with all sides and angles the same is called a "regular polygon."
A polygon with 6 sides has 6 angles.
The exterior angles of any polygon add up to 360.