None normally because a pentagon is 2 dimensional 5 sided shape whereas a sphere is a 3 dimensional globular shape.
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no it cant be unless you use pentagons and octagons like on a soccer ball * * * * * That is an unbelievably rubbish answer! Tessellation - unless otherwise specified - refers to covering a 2-d surface, not the surface of a sphere. Normal soccer balls do not have pentagons and octagons but pentagons and hexagons.
Pentagons (including convex pentagons) have five sides. (The prefix penta- is greek for 5)
No, pentagons to not have right angles.
The Pentagon
2 faces