The first person can be selected in one of seven ways. Having selected him, the second can be selected from the remaining six in six ways. So there would appear to be 7*6 ways of selecting the couples shaking hands.
But, x shaking y's hand is the same handshake as y shaking x's hand. Thus each handshake is conted twice, So the total number of handshakes is 7*6/2 = 21
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For everyone to shake hands with everyone else, there are 21 handshakes. (below copied from my answer of a similar question) This is an arithmetic progression and can be solved with the equation Sn=(1+(n-1))(n-1)/2 where Sn is the total sum of handshakes for n people. NB: I have used n-1 instead of n in the equation for the sum of an arithmetic progression, because you're not really going to shake hands with yourself, so you don't include the nth term, in this case 7. Alternatively, you can solve this geometrically by drawing a heptagon, drawing lines between all the vertices, and then adding all the lines up.
72
First person shakes hands 19 times, second person 18 etc, a total of 190.
The two hands make an angle of 155 degrees (and 205 degrees).