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Trigonal pyramidal. As has 5 valence electrons. It forms single bonds with each of the F atoms, donating one electron to each bond. This leaves 2 unbonded electrons, or a single lone pair. Thus the molecule has 4 different groups attached to As, and the electron configuration is tetrahedral. A tetrahedral configuration with one lone pair results in a trigonal pyramidal molecular geometry.

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Q: What is the molecular geometry of AsF3?
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