Yes because angles around a point add up to 360 degrees and a square has corner angles of 90 degrees
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No, but an octagon and a square can tessellate.
No, a square and a pentagon cannot tessellate together. In order for two shapes to tessellate, their angles must add up to a multiple of 360 degrees. A square has angles of 90 degrees, while a regular pentagon has angles of 108 degrees. Since 90 and 108 do not add up to a multiple of 360, these shapes cannot tessellate together.
No.
square and octagon
Square.