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There are regular polygons (with 3, 4 and 6 sides).There are irregular convex polygons (with 3, 4, 5 or 6 sides). There are [irregular] concave polygons with various numbers of sides.
Regular polygons with 3, 4 or 6 sides.
hexagon
The hexagon is the only one that has exactly 6.All polygons with 6 or more sides have at least 6 interior angles.
Draw one. Every time you move your pencil to draw a new side, you create a new angle.