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There are 2 syllables. Mill-ions.
polyatomic ions are those ions which carry more than one atom,we can say that a group of atoms having single charge( which may be positive or negative) are polyatomic ions.
Phosphate ions, sulfate ions, potassium ions, urea, uric acid, creatine.
H+ ions would not flow.
The metals and non metals which tend to form positive ions are cations. It is because of their electronic configuration.