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The volume is still 100 ml: the shape does not affect the volume.
A cube with sides measuring 100 cm in length has a volume of 1 million cm3
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100 grams of water at standard temperature and pressure has a volume of 100 cubic centimeters or 100 millilitres. The volume of 100 grams of any other substance will depend on its specific gravity or density: if less than that of water, it will have a greater volume; if greater than that of water, it will have a smaller volume.
If the base of a cube is 100cm then the base must measure 10cm by 10cm. so, as it is a cube its height must also be 10cm. Therefore the volume of the cube is 10cm x10cm x10cm which equals 1000 cubic cm.