No, they stopped making U.S. currency in denominations above $100 in 1945.
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In an effort to combat organized crime, President Nixon issued an executive order in 1969 that prevents banks from distributing high-denomination bills, any that they have or receive are to be sent back to the Treasury. The order didn't officially withdraw the bills so technically they're still legal tender but they're long gone from circulation.
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No you Ding-dong!
one hundred dollars is equal to twenty times five dollars, but there are NO five dollar bills in a hundred dollar bill.
no There's no longer even a thousand dollar bill anymore.
A US or Canadian nickel is worth 5 cents. A five dollar bill is worth 500 cents. Thus a five dollar bill is equivalent to 100 nickels.
You would get 10 five dollar bills.