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You channel your chi into a transmutation circle when you have the ingredients to make what you want. Than think about what you want to make.
The origin for transmutation circles came from the anime FullMetal Alchemist. Transmutation circles are formed using the symbols and keys of real life alchemy used during the Middle Ages. Their meanings and the meaning interpreted into the show are very similiar, but that is only done to encourage the belief of it's existence. Creating works that can be linked to our past or everyday lives tends to make us believe in it's existence. So, to answer your question, transmutation circle do not work. They were created to endorse a now famous Japanese anime. and that is all they will ever be.
You draw a circle around a circle.
Its the distance from the center of the circle to the edge of the circle.
The cord of a circle that contains the center of that circle is a diameter of that circle.