You could just call it a 100-gon. In English there's no word for a 100 sided polygon. in Latin, it would be centagon, using the prefix -centa meaning 100.
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The correct term for a one hundred sided polygon is a hectacontagon.
A pentahectagon or a pentacentagon.
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A 9 sided polygon is a Nonagon.
Some examples are: 5 sided polygon is a pentagon, 6 sided polygon is an hexagon and an 8 sided polygon is an octagon